Coffee was first imported to Italy. The vibrant trade between the Italian city of Venice and the Muslims in North Africa, Egypt, and the East brought a large variety of African goods, including coffee, to this leading European port. Venetian merchants decided to introduce coffee to the wealthy in Venice, charging them heavily for the beverage. In this way, coffee was introduced to Europe. Coffee became more widely accepted after it was "baptized" by Pope Clement VIII in 1600 despite appeals to ban the Muslim drink. The first European coffee house (apart from those in the Ottoman Empire, mentioned above) was opened in Italy in 1645.
So, the Muslims in North Africa first introduced coffee to Europe.